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Additional info for Alternative Solvents for Green Chemistry: 2nd Edition
However, there are limitations to this procedure, as the dye molecule used is only reflecting limited types of molecular interaction based on its own structure. To overcome these limitations, the Kamlet-Taft parameters (a, b and p*) were introduced and used a series of seven different dyes. 11); p* is a measure of general polarity/polarizability (excluding H-bonding effects). 53 The effect of solvent polarity on chemical systems including reactions rates and equilibria can be quite significant.
Fu and L. Phan, Green. , 2012, 14, 124521259. 54. S. M. Payne and F. M. , 2010, 12, 164821653. 55. N. Jiang, D. Vinci, C. L. Liotta, C. A. Eckert and A. J. Ragauskas, Ind. Eng. Chem. , 2008, 47, 6272631. 56. D. Vinci, M. Donaldson, J. P. Hallett, E. A. John, P. Pollet, C. A. Thomas, J. D. Grilly, P. G. Jessop, C. L. Liotta and C. A. Eckert, Chem. , 2007, 142721429. 17/11/2013 09:00:38. 1 Introduction Legislation provides a framework to ensure the safe use of solvents and can be seen as both a barrier and also an opportunity to encourage the greater use of greener solvents.
Manley, B. A. Pearlman, A. Wells, A. Zaks and T. Y. Zhang, Green. , 2007, 9, 4112420. 37. A. M. Rouhi, Chem. Eng. News, 2002, 80, 30233. 38. R. A. Sheldon, Chem. Soc. , 2012, 41, 143721451. 39. G. P. Taber, D. M. Pfisterer and J. C. Colberg, Org. Proc. Res. , 2004, 8, 3852388. 40. P. G. , 2011, 13, 139121398. 41. M. J. Raymond, C. S. Slater and M. J. , 2010, 12, 182621834. 42. C. J. Welch, T. Brkovic, W. Schafer and X. , 2009, 11, 123221238. 43. Y. Gaber, U. Toernvall, M. A. Kumar, A. M. Ali and R.
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